MTL - She Doesn’t Want the Face-Blind Husband - Chapter 54

There was a Senior Brother and a Junior Sister. One of them was transmigrated to this world and had cheats while the other was the reincarnation of a Great Emperor.

A good-for-nothing man married a beautiful girl but was kicked off the bed on the wedding night. Furiously, he wrote a bill of divorce and ran away.
He was schemed a car accident in which he nearly lost his life. However, it turned out to be a blessing. He swallowed the soul that passed through the outer world, thus obtained superb medical skills and martial arts.
Later on, with the silver needles and invincible martial arts, he embarked on the road of counterattacks and was committed to his great dreams.

- Description from Novelupdates

[Ding........ ][System Binding.......][10%..........][20%..........][40%..........][60%..........][80%..........][100%........][ Congratulations, Host! The Strongest Family System has been bound! ]----------------------------“Huh? I’ve transmigrated…” Arthur muttered, his voice barely above a whisper as he surveyed his bewildering new surroundings. Confusion washed over him like a tidal wave.-----------------------------Arthur was just an ordinary corporate worker, an overworked cog in the relentless machine of corporate life.After seven grueling days of nonstop overtime, his body finally gave out, collapsing right before his computer screen at home.He thought that was it; he thought he was dead. But little did he know, fate had something extraordinary in store for him.Instead of fading into oblivion, Arthur found himself thrust into a vast and unfamiliar world, one ten times larger than Earth itself!To his astonishment, he had become the head of the Osborn family, a once-mighty lineage now teetering on the brink of destruction.Bound by the standard configuration for all transmigrators: The System which is the [Strongest Family System ], Arthur faced an epic challenge: to transform the faltering Osborn family into the most powerful dynasty in existence.Join Arthur on this thrilling adventure as he navigates treacherous waters filled with intrigue, power, influence and danger.Can he lead a declining family back to glory and secure their place at the top?

Once she crossed through, she actually became the disfavored third WangFei?